Answers · States and changes of state
Where does the heat go? — answer key
Check meaning, not exact wording. These are teaching points, not official Cambridge marks.
1. SQ5 · Practice
Model answer. 44 °C. The first flat section, B to C, is where solid P melts: the temperature stays constant while it changes state.
A full answer includes
- I chose 44 °C.
- I used the first flat section, B to C, as evidence.
Also accept
- 44 °C, because the graph is first flat from B to C, where P melts.
Watch for
- “The melting point is where heating starts, at 20 °C.” — At A the solid is simply being heated. The melting point is the temperature of the first flat section, where the temperature stops rising while the solid melts.
2. SQ6 · Practice
Model answer. Statements 1 and 2. Evaporation happens only at the surface, at temperatures below the boiling point: some fast-moving particles near the surface escape. Bubbles throughout the liquid and a fixed temperature describe boiling.
A full answer includes
- I chose statements 1 and 2.
- I explained that some fast-moving particles at the surface escape, even below the boiling point.
Also accept
- 1 and 2: evaporation happens at the surface below the boiling point, because some surface particles have enough energy to escape.
Watch for
- “Evaporation is just slow boiling.” — Boiling happens throughout the liquid at the boiling point. Evaporation happens only at the surface, at temperatures below it.
3. SQ7 · Practice
Model answer. Boiling: liquid P is turning into a gas. The energy supplied is used to overcome the forces of attraction between the particles and separate them, not to make them move faster. So the temperature stays at 150 °C until all of P has boiled.
A full answer includes
- I named boiling: liquid P turning into a gas.
- I said the energy is used to overcome the forces of attraction between the particles.
- I said the particles don't move faster on average, so the temperature stays constant.
Also accept
- Boiling. The energy overcomes the forces of attraction between particles instead of increasing their kinetic energy, so the temperature is constant.
Watch for
- “No energy is going in while the graph is flat.” — The heater still supplies energy. It goes into separating the particles, not into raising their average speed.
4. SQ8 · Practice
Options as numbered on the pupil sheet: 1 — Liquid water warms up; 2 — Ice warms up; 3 — Water boils; 4 — Ice melts.
Model answer. Ice warms to 0 °C; ice melts at 0 °C; liquid water warms to 100 °C; water boils at 100 °C. The temperature stays constant during melting and boiling, because the energy overcomes forces of attraction between molecules instead of making them move faster.
A full answer includes
- Order: ice warms, ice melts, water warms, water boils.
- I said the temperature does not rise during melting and boiling, because the energy changes the state instead.
Also accept
- Ice warms, ice melts, water warms, water boils; no temperature rise while melting or boiling, because the energy changes the state.
Watch for
- “Water boils as soon as all the ice has melted.” — The liquid first has to warm from 0 °C to 100 °C. Only then does it boil.
5. SQ13 · Practice
Model answer. It is evaporating. At 70 °C the water is below its boiling point, so molecules leave only from the surface: some move fast enough to escape. Hot water evaporates quickly, which is why the level fell. If it started to boil, at 100 °C, bubbles of water vapour would form throughout the liquid.
A full answer includes
- I said the water is evaporating, not boiling.
- I explained that some fast-moving molecules escape from the surface, below the boiling point of 100 °C.
- I said boiling would show bubbles of vapour forming throughout the liquid, at 100 °C.
Also accept
- Evaporating: 70 °C is below the boiling point and molecules leave only from the surface; boiling would make bubbles throughout at 100 °C.
Watch for
- “The water is hot and losing volume, so it is boiling.” — Hot is not the same as boiling. Below 100 °C water only evaporates from its surface; boiling makes bubbles form inside the liquid.
6. ST2 · Apply
Model answer. (a) The temperature rises to −114 °C, stays flat while the ethanol melts, rises to 78 °C, stays flat while it boils, then rises to 100 °C as a gas. (b) Evaporation. At 60 °C the ethanol is below its boiling point, so particles escape only from the surface; the warm bath makes this faster. At 78 °C it would boil: bubbles of ethanol vapour would form throughout the liquid, and its temperature would stop rising.
A full answer includes
- The curve is flat at −114 °C while solid and liquid ethanol are both present (melting).
- The curve rises between the flat parts and is flat again at 78 °C while liquid and gas are both present (boiling); then it rises.
- (b) Evaporation: below its boiling point, some fast-moving particles escape from the surface; at 78 °C bubbles of vapour would form throughout the liquid as it boils.
Also accept
- Flat at −114 °C (melting) and 78 °C (boiling), rising between; at 60 °C it evaporates from the surface, and at 78 °C it would boil with bubbles throughout.
Watch for
- “The ethanol in the warm bath must be boiling, because it is losing volume.” — 60 °C is below its boiling point and no bubbles form inside. Particles escape from the surface: that is evaporation.